Partial Melting Of Mantle Peridotite Research Articles

Triassic oceanic–continental transition of the Ganzi–Litang Ocean basin: Evidence from high-Mg andesites and Nb-enriched basalts in the Litang area, Eastern Tibet

Petrological evidence of the oceanic–continental transition of intra-oceanic arcs enables the identification and reconstruction of the transformation of ocean basins into continents. In this study, we present new elemental and Sr–Nd isotopic compositions and zircon U–Pb ages for Triassic andesites and basalts in the Litang area, Eastern Tibet. Andesites in Cunge and basalts in Juewu contain zircon grains with U–Pb ages of 246 ± 2 and 248 ± 2 Ma, respectively, indicating a Middle Triassic origin. Andesites in Cunge have high SiO2 contents (53.1–56.5 wt%), MgO contents (5.15–7.13 wt%), and Mg# values (54–61), similar to Sanukite-type high-Mg andesites. Basalts in Juewu have high TiO2 (1.43–1.80 wt%) and Nb (12.5–20.2 ppm) contents, and high Nb/U and (Nb/La)N values, typical of Nb-enriched basalts. The andesites and basalts were both characterized by low (87Sr/86Sr)i values (0.7033–0.7044) and positive εNd(t) values (+4.2–+4.8). Therefore, interactions between melt from the subducting slab and mantle wedge peridotite formed andesites in Cunge, whereas the partial melting of mantle peridotite metasomatized by an adakitic melt (produced by the melted slab) formed basalts in Juewu. The findings of this study indicate that the formation of the andesites and basalts in the Litang area were related to intra-oceanic subduction magmatism, which was the product of the westward subduction of the Ganzi–Litang Ocean basin in the Middle Triassic.

Deep segregation and crystallization of ultra-depleted melts in the sub-ridge mantle

Partial melting of mantle peridotite from which considerable amounts of melt have been extracted during prior melting episodes generates melts characterized by low incompatible element contents and very low ratios of highly to moderately incompatible elements, so-called ‘ultra-depleted’ melts. Reaction of peridotite with percolating ultra-depleted melts has been inferred from petrological-geochemical studies of abyssal peridotites and ophiolites. But so far, direct evidence for the existence of ultra-depleted melts, only comes from rare melt inclusions. Here, we show that a pyroxenite layer within abyssal peridotite from the Mid Atlantic Ridge (8°N, Doldrums Fracture Zone) formed by crystallization of a segregated melt that is highly depleted in incompatible elements, at >27 km-depth beneath the ridge axis (at T ∼ 1250 °C), and with little or no modification by interaction with the host harzburgite. During exhumation, the pyroxenite experienced decompression and partial re-equilibration under plagioclase-facies conditions (∼1060 °C and ∼ 15 km depth). The high Hf isotope ratio (εHf = 40.3) of the pyroxenite clinopyroxene is inherited from a melt sourced from an ultra-depleted peridotite that evolved with high Lu/Hf. The associated MORB-like Nd isotope ratios (εNd = 10.6), however, imply a long-term evolution of the source peridotite with composition moderately depleted in incompatible elements (rather low Sm/Nd). These compositions are different from the host harzburgite, but typical for peridotites that have melted and partially reacted with migrating melts in ancient times. Hence, the pyroxenite investigated here is a partial melt from an ultra-depleted peridotite that has become re-enriched in incompatible elements and clinopyroxene. This melt crystallized in the oceanic lithosphere, and partially re-equilibrated at low pressure during exhumation. Overall, our results show that renewed melting of ultra-depleted peridotites with a complex history of prior melting and melt-rock reaction occurs, and that such melts migrate through the sub-ridge mantle, and can thus contribute to mid ocean ridge magmatism, although to a still unknown extent.

Geochronology and Geochemistry of the Early Paleozoic Ore‐host Volcanic Sequence in the Kalatag Area, East Tianshan, NW China: Implications for the Tectonic Evolution

AbstractThe East Tianshan contains many late Paleozoic magmatic and polymetallic deposits. Recent studies demonstrate that the early Paleozoic volcanic rocks discovered in the northern region of East Tianshan can be subdivided into the Daliugou, Hongliuxia and Kalatag formations. Here, we report zircon U‐Pb ages of volcanic rocks and quartz diorite porphyry, together with whole‐rock geochemical and Sr‐Nd isotope data of early Paleozoic volcanic rocks, in order to investigate their petrogenesis and geodynamic setting. Zircon U‐Pb analyses of the rocks suggest that the Kalatag Formation formed at ca. 438–413 Ma. Geochemical characteristics of the early Paleozoic volcanic rocks exhibit typical subduction‐related features. They have high Mg#(44–75), positiveεNd(t) values (0.25–7.88), low87Sr/86Sr ratios (0.70457 to 0.70588) and young two‐stage Hf isotope model ages (551–446 Ma), consistent with a depleted mantle origin with limited crustal contamination. The basaltic andesite and andesite have relatively high MgO contents (6.1–9.4 wt%), suggesting that they belong to high‐magnesian andesites. They were most likely derived from the partial melting of mantle peridotite caused by the addition of fluids released by subducted oceanic slab. Based on regional geology, geochemical characteristics and previous studies, we infer that the southward subduction of the Junggar Ocean slab resulted in the generation of early Paleozoic volcanic rocks and arc setting‐related metallogenic systems in the Kalatag area.

Geochemistry, zircon U–Pb geochronology and Hf isotope of the early Permian gabbro and high-Mg diorites from the Zhusileng–Hangwula Belt in the northern Alxa area: Petrogenesis and tectonic implications

AbstractAs the southernmost part of the central segment of the Central Asian Orogenic Belt, the northern Alxa area is characterized by abundant Permian magmatism and records key information on the geological evolution of the Palaeo-Asian Ocean. This study reports new zircon U–Pb and Lu–Hf isotopic and whole-rock geochemical data of the early Permian (285–286 Ma) Huisentala gabbro and Huodonghaer diorites from the Zhusileng–Hangwula Belt in the northern Alxa area. The gabbro is characterized by high Al, Ca, Mg# and light rare-earth elements, and low K, P and high field strength elements (e.g., Ti, Nb and Ta). Furthermore, the gabbro shows heterogeneous zircon ϵHf(t) value (−2.5 to +2.6). The Huodonghaer diorites show high MgO (3.46–6.32 wt%), Mg# (49–58), Sr (408–617 ppm) and Ba (223–419 ppm), and low FeOT/MgO (1.27–1.83) and TiO2 (0.48–0.90 wt%), with geochemical features similar to the high-Mg andesite/diorite. They show radiogenic zircon ϵHf(t) values of +1.2 to +4.9 and high Th/Nb ratios. These features suggest that the Huisentala gabbro and the Huodonghaer diorites were derived from the partial melting of mantle peridotite that was metasomatized by subduction-related fluids and by subducted sediment-derived melts, respectively.

The role of recycled oceanic crust in the alkaline basalts: Evidence from Zn isotopic compositions of alkaline basalts from the Madeira hotspot (eastern North Atlantic)

Plate tectonic processes introduce oceanic crust (as eclogite) into the sources of oceanic island basalts (OIB). The fate of this recycled material in the deep mantle is still poorly understood. Here we present a systematic study of Zn isotopes on well-characterized alkaline basalts (<5 Ma) from the Madeira Islands in the eastern North Atlantic. Our analyses show that the δ66Zn values of alkaline basalts range from 0.25‰ to 0.34‰, with an average of 0.30 ± 0.05‰ (2SD, N = 15), which is similar to the average of mid-ocean ridge basalts (MORB) (0.28 ± 0.03‰, 2SD), and ∼ 0.14‰ higher than that of the asthenospheric mantle (0.16 ± 0.06‰, 2SD). However, these alkaline basalts have higher Zn/Fe ratios (up to 14.20) than MORB (generally less than 12). Model calculations show that the partial melting of mantle peridotite cannot simultaneously produce the observed MORB-like δ66Zn values and trace element ratios. After excluding the effects of post-eruption alteration, crystal fractionation, and the assimilation of crustal materials during magma upwelling on Zn isotopic compositions of the studied samples, we suggest that the MORB-like δ66Zn values reflect the mixing of peridotite melt and eclogite/pyroxenite-derived melt in the magma source of the Madeira hotspot. This is supported by trace element ratios and radiogenic isotopes, such as high Zn/Fe and Dy/Yb ratios and 206Pb/204Pb values. Our new data provide independent evidence in support of the important role of recycled oceanic crust in the source and generation of alkaline OIBs, and also highlight that such sources are not ubiquitously carbonated.

Chromitite deposits of Ufaley ultramafic massif (South Urals)

Data on the morphology, composition, textural and structural features of chromite deposits of the Ufaley ultramafic massif are presented. The mineralogical and compositional features of the host ultramafic rocks allow us to interpret them as depleted restite from partial melting of mantle peridotites. Relatively wide variations in the composition of ore-forming chromian spinel grains (#Cr 0.6–0.8) and noticeable metamorphism of disseminated ores with replacement of chromite by Cr-magnetite are noted. It is assumed that chromitite bodies were initially formed under the conditions of the upper mantle by a rheomorphic mechanism, and then their structural and geochemical transformation took place in the collisional setting of the upper part of the crust. Flattened bodies of disseminated chromitites have been preserved near competent gabbroid blocks, while other deposits have been transformed into lenses and podiform bodies of densely disseminated and massive ores of smaller size. The “cold tectonics” of the crustal stage led to the disintegration of deposits and the simultaneous local enrichment of deformed chromitite bodies.

Geological setting and genesis of the Kurmansky gabbro-trondhjemite massif (Middle Urals)

This paper reports the results of petrogeochemical studies of the Kurmansky gabbro-trondhjemite massif (eastern slope of the Middle Urals), lying in the western part of the large Reftinsky allochthonous block within the accretion East Uralian megazone. The relevance of this study is determined by the uncertainty in geodynamic setting and formation conditions of the rock massif and its role in the evolution of the Ural Mobile belt. We specified the countours of the massif. It is shown that the rocks were resulted from spatiotemporal convergence of partial melting in the mantle and lower crust at the island-arc stage of the Ural Mobile belt evolution. Partial melting of mantle peridotite, under the influence of an aqueous fluid rising from the subduction zone, initiated the occurrence of basite melts. The separation of the melt and its subsequent evolution to the compositions of gabbrodiorite and diorite took place at Ptot=10 kbar. Trondhjemites were formed as a result of partial melting of amphibolites at Ptot≥8 kbar, PH2O=0.1–0.2 kbars. The crystallization of trondhjemites in the crust was accompanied by the wollastonite skarns on contact with carbonate rock and xenoliths culminated at mesoabyssal level, Ptot=PH2O=1 kbar. The comparison between the composition of Kurmansky gabbro-trondhjemite massif and the island-arc- and collision-related magmatic suites in the region allowed us to assume that the Kurmansky massif belongs to the independent Early Devonian (?) gabbro-trondhjemite complex of island arc origin. The rock metamorphism conditions were evaluated, with the transformations supposedly related to the accretion of early island arc complexes at the Murzinsky-Aduysky microcontinent, which took place in the Devonian.

Late Neoarchean geodynamic regime of the northeastern North China Craton: Constraints from metamorphosed volcanic rocks of the Anshan-Benxi greenstone belt

The Anshan-Benxi greenstone belt in the northeastern North China Craton preserves ∼ 3.88 Ga to ∼ 2.5 Ga lithologies that exhibit based secular trends in their geological signatures and hosts large amounts of valuable Neoarchean banded iron formations. However, whether plume or subduction mechanism responsible for those iron deposits remains confusing. This contribution focuses on the metamorphosed volcanic rocks and aims to constrain their geodynamic regime, based on temporal and spatial distributions, petrogenesises and tectonic characteristics. The late Neoarchean metamorphosed volcanic rocks of the Anshan-Benxi greenstone belt are prominently exposed in the Waitoushan-Gongchangling-Benxi area and consist of plagioclase amphibolites, amphibole/mica plagioclase gneisses and amphibole/mica two-feldspar gneisses. All 107 metamorphosed volcanic rock samples may be geochemically and petrographically classified as tholeiites, tholeiitic to calc-alkaline basalts, andesite, and dacite-rhyolite. The tholeiites are characterized by approximately flat REE patterns with negligible Eu anomalies and show negative Nb anomalies on primitive normalized multiple element diagrams, consistent with a back-arc basin basalt origin. The tholeiitic to calc-alkaline basalts have slightly heavy REE-depleted patterns and obvious negative Nb anomalies, which were likely produced by partial melting of mantle peridotites that were metasomatized by subducted slab-released fluids and melts. They may be comparable to island arc basalts. The andesites exhibit notably high MgO, Mg# and transition metal element contents, low FeOT/MgO ratios, fractionated REE patterns and evident negative Nb, Ta and Ti anomalies, which are akin to Phanerozoic high magnesian andesites and are melts of mantle peridotites that were previously metasomatized by subducted slab melts/fluids. The dacite-rhyolites have the highest SiO2 and lowest MgO, Cr and Ni contents and were derived from intracrustal remelting.The zircon U-Pb dating results reveal that the arc tholeiitic to calc-alkaline basalt-andesite-dacite-rhyolite assemblages erupted at ∼ 2.57 Ga – ∼2.52 Ga and back-arc basin basalt lithological association at ∼ 2.55–2.52 Ga. Furthermore, both the arc basalt-andesite-dacite-rhyolite and back-arc basin basalt associations are predominantly exposed within the Waitoushan-Gongchangling-Benxi range of the northeastern Anshan-Benxi greenstone belt. Therefore, we suggest that the Waitoushan-Gongchangling-Benxi area represents a rear-arc to back-arc zone, which was subsequently subjected to consistent NE-SW compression (σ1) and top-to-northeast kinematic features during back arc closure and underwent up to high amphibolite facies metamorphism. However, the Anshan area in the southwestern range of the Anshan-Benxi greenstone belt preserves large amounts of thick-bedded metasedimentary rocks instead of back-arc and arc volcanic rocks, which indicates a stable depositional environment in a typical back arc basin depositional zone. The supracrustal rocks within the back arc basin depositional domain underwent NE-SW compression (σ1) and top-to-southwest kinematic features and mostly experienced greenschist facies metamorphism.These crust-mantle interaction features inferred by metamorphosed volcanic rocks in the Anshan-Benxi greenstone belt, spatial and temporal variations in the lithological assemblages, together with the style of structural deformations, indicate a late Neoarchaean geodynamic evolution from SW-dipping subduction to arc-back-arc development and collisions between ancient continental blocks and arcs.

Depletion of the upper mantle by convergent tectonics in the Early Earth

Partial melting of mantle peridotites at spreading ridges is a continuous global process that forms the oceanic crust and refractory, positively buoyant residues (melt-depleted mantle peridotites). In the modern Earth, these rocks enter subduction zones as part of the oceanic lithosphere. However, in the early Earth, the melt-depleted peridotites were 2–3 times more voluminous and their role in controlling subduction regimes and the composition of the upper mantle remains poorly constrained. Here, we investigate styles of lithospheric tectonics, and related dynamics of the depleted mantle, using 2-D geodynamic models of converging oceanic plates over the range of mantle potential temperatures (Tp = 1300–1550 °C, ∆T = T − Tmodern = 0–250 °C) from the Archean to the present. Numerical modeling using prescribed plate convergence rates reveals that oceanic subduction can operate over this whole range of temperatures but changes from a two-sided regime at ∆T = 250 °C to one-sided at lower mantle temperatures. Two-sided subduction creates V-shaped accretionary terrains up to 180 km thick, composed mainly of highly hydrated metabasic rocks of the subducted oceanic crust, decoupled from the mantle. Partial melting of the metabasic rocks and related formation of sodic granitoids (Tonalite–Trondhjemite–Granodiorite suites, TTGs) does not occur until subduction ceases. In contrast, one sided-subduction leads to volcanic arcs with or without back-arc basins. Both subduction regimes produce over-thickened depleted upper mantle that cannot subduct and thus delaminates from the slab and accumulates under the oceanic lithosphere. The higher the mantle temperature, the larger the volume of depleted peridotites stored in the upper mantle. Extrapolation of the modeling results reveals that oceanic plate convergence at ∆T = 200–250 °C might create depleted peridotites (melt extraction of > 20%) constituting more than half of the upper mantle over relatively short geological times (~ 100–200 million years). This contrasts with the modeling results at modern mantle temperatures, where the amount of depleted peridotites in the upper mantle does not increase significantly with time. We therefore suggest that the bulk chemical composition of upper mantle in the Archean was much more depleted than the present mantle, which is consistent with the composition of the most ancient lithospheric mantle preserved in cratonic keels.

Osmium isotope evidence for rapid melt migration towards the Moho in the Oman ophiolite

The oceanic crust, covering two-thirds of the Earth's surface, is formed along mid-oceanic ridges by crystallization at shallow levels of melts formed at depth by partial melting of mantle peridotite. Yet, the process of melt transport to the ridge axis remains poorly understood. Ophiolites, which provide a window into the uppermost mantle, contain dunite bodies often interpreted as relics of melt flow conduits, formed by pyroxene dissolution during melt-peridotite interaction. Here, we present structural and geochemical data on peridotites from the southeastern Oman ophiolite where three types of dunite, corresponding to the Moho transition zone (MTZ), the main and basal mantle sections, are identified. We focus on osmium isotopes, which are particularly well-adapted to tracing melt flow through peridotites. Osmium isotope signatures from host harzburgites accord with abyssal peridotite values and do not vary systematically with setting. In contrast, dunite Os compositions depend on structural context. Basal dunites display compositions similar to harzburgite values, while MTZ dunites have highly radiogenic compositions similar to those of the overlying crust, requiring extensive interaction with melts more radiogenic than MORB. Modeling shows that melts percolating through and equilibrating with dunite channels would acquire unradiogenic compositions, inconsistent with the observed Os signatures of MTZ dunites and lower crust. Thus, our findings require melt transport without equilibration with dunite or harzburgite, arguing for rapid or at least chemically isolated melt migration from the mantle source to the Moho.

Evolution of Archean Sanukitoids from the Otto Stock by Magma Mixing and Na–K Metasomatism: Evidence from Petrological Observations and Lithium Isotope Geochemistry

Abstract Petrogenetic models for the genesis of Archean sanukitoids are diverse in the literature but most point to the initiation of plate tectonics and the construction of the first proto-continents during the Late Archean. These rocks include diorites, monzonites, monzodiorites, quartz monzodiorites, trachyandesites, granodiorites and tonalites, and are defined as having SiO2 = 55–60 wt%, Na2O + K2O = 6 wt%, MgO &amp;gt; 6 wt%, Mg# &amp;gt; 60, Ni–Cr &amp;gt; 100 ppm, Sr and Ba = 600–1800 ppm, chondrite-normalized Ce and Yb values of 80–250 and 4–10, respectively, and no Eu anomalies. Petrogenetic models include the partial melting of mantle peridotite previously metasomatized by fluids of crustal or mantle origin, partial melting of subducted slabs and assimilation of peridotite, and partial melting of undepleted peridotite with subsequent mixing with tonalite–trondhjemite–granodiorite (TTG) crustal partial melts and addition of carbonatite, all of which may or may not include subsequent differentiation by fractional crystallization. Here, extraordinary textural relations unequivocally show that at the Late Archean Otto stock, Abitibi, Canada, sanukitoids resulted from the assimilation of clinopyroxenite by monzonitic magmas and coeval magmatic–hydrothermal Na–K metasomatism. The metasomatized monzonites (± quartz), melanogranites, granodiorites, and sanukitoidal melanoporphyries were subsequently cut by swarms of lamprophyre dykes hosting a different set of hydrothermal alteration assemblages, including propylitic alteration, biotitization, chloritization, and pyritization, along with associated enrichments in Au. These alterations are shown to be associated with the nearby Cadillac–Larder Lake Fault Zone and the world-class Kirkland Lake gold deposit. The Li isotopic compositions of these rocks correlate with Au concentrations and range from magmatic values of ∼ +4 ‰ up to +10·4 ‰ in Na–K metasomatized and Au-depleted rocks, and from magmatic values of ∼4 ‰ down to 0·6 ‰ in rocks hosting propylitic, chloritic, and biotitic alteration and Au enrichments of up to 2·9 ppm Au.

To view on evolution of primary texture of Aliabad chromite (NE Forumad), petrogenesis and tectonic setting

Ali abad chromites mines (north east of Forumad) are as a part of chromites assemblage dependent on ophiolite Sabzevar that are located in NW Sabzevar city. Chromitites deposits in these mines have been located as irregular lenses and layered or banded along with pods of dunite in depleted harzburgite. In attention to mineralogy observation, incongruent melting of orthopyroxenes and exsolution lamellae of clinopyroene in the orthopyroxenes, indicate that these rocks were originally formed at mantle pressures and temperatures conditions. Mineralography study on the textures and structures of Ali abad chromites indicate two types main textures that are primary and secondary. The primary textures and structures include massive and disseminated or separated grain. The milonitic, brecciated and tensional textures are from secondary types in chromites. On the basis of geochemical results the structural formula are calculated as the chromite minerals [(Mg,Fe2+)O (Cr,Al,Fe3+)2O3].These studies represent height percent Cr2O3 chromite mineral in disseminated texture than massive textures. Geochemical study on the chromitite area, site them in height Cr types and associated to podiform type that are originated from a parent melt with boninitic character resulting from high degree of partial melting of mantle peridotite in Supra Subduction Zone (SSZ).

Geochronology, geochemistry and petrogenesis of the Neoarchean magmatism in the Jiefangyingzi area, northern North China Craton: Implications for crustal growth and tectonic affinity

The Bayan Obo-Duolun-Chifeng-Kaiyuan fault is considered as the craton-orogen boundary between the northern North China Craton (NCC) and the Central Asian Orogenic Belt (CAOB). However, locations of this boundary from Duolun, Chifeng to Kaiyuan have not been well constrained. The Jiefangyingzi area northeast to Chifeng is located at the junction of the Bainaimiao arc belt and northern NCC, and has long been regarded as part of the Bainaimiao arc belt of the CAOB. This paper presents new LA-ICP-MS zircon U-Pb geochronological, whole-rocks geochemical and Nd-Hf isotopic data of some recently identified Neoarchean magmatic rocks from the Jiefangyingzi area. These rocks consist mainly of amphibolites, dioritic gneisses, quartz dioritic gneisses, tonalitic gneisses and trondhjemitic gneisses formed at 2569–2536 Ma and minor amphibole plagioclase gneisses formed at ca. 2640 Ma, and are distributed in an east–west belt that is about 13 km long and 1.5 km wide. Geochemical and Nd-Hf isotopic compositions suggest that the amphibolites were derived from partial melting of a depleted mantle that was metasomatized by subduction-derived fluids with significant crustal contamination, and the dioritic gneisses were generated by partial melting of mantle peridotite metasomatized by slab-melts. The quartz dioritic and tonalitic gneisses originated from high degree partial melting of the subducted oceanic crust with garnet-bearing amphibolite facies in the residue, while the trondhjemitic gneisses originated from low degree partial melting of the thickened mafic lower crust with eclogite facies in the residue due to underplating of mafic magmas. The occurrences of Neoarchean basement rocks, combined with previous Nd-Hf isotopic data of the late Paleozoic magmatic rocks, suggest that the Jiefangyingzi area has a tectonic affinity with the Eastern Block of the NCC rather than the CAOB, and the craton-orogen boundary between the northern NCC and the CAOB should be situated in places north to the Jiefangyingzi area. Our results support that the late Neoarchean (2.6–2.5 Ga) is also a period of crustal growth as well as extensive reworking of the 2.9–2.7 Ga ancient crust in the northwestern margin of the Eastern Block of the NCC. In addition, the transition from tonalite-trondhjemite-granodiorite (TTG) and other potassium-poor granitoid gneisses to crustal-derived potassium-rich granitoid gneisses at the end of Neoarchean (ca. 2.53 Ga) marked the initial cratonization of the NCC and ca. 2.53 Ga is a critical transformation period of maturation of the continental crust in the NCC.

High-Mg andesitic rocks formed through crustal magmatic differentiation

High-Mg andesitic rocks are enriched in both compatible (Mg, Cr and Ni) and incompatible elements (Si, Ba and Sr), which indicates the complexity of their petrogenesis. Models involving hybridization of the mantle sources and input of adakitic melts have been invoked, but struggle to explain the low Mg# values (<0.65) of some low Sr/Y (<40) high-Mg andesitic rocks, because these rocks cannot represent primary melts (Mg# ≥ 0.72) produced by the partial melting of mantle peridotite. This study presents a petrological and geochemical analysis of the Xinsi diorite (443 ± 3 Ma) and Tiechang gabbro (440 ± 3 Ma) from the Early Paleozoic Wuyi-Yunkai Orogen in South China, and demonstrates the role of magmatic differentiation in the petrogenesis of high-Mg andesitic rocks. These rocks contain high SiO2, MgO, Ba and Sr concentrations with low Mg# values (≤0.69) and Sr/Y ratios (≤16.7), resembling typical low Sr/Y high-Mg andesitic rocks. Amphiboles and clinopyroxenes in the Xinsi diorite contain variable contents of Ba and Sr, both of which negatively correlate with Mg#. This indicates that their parental melts had low Ba and Sr and underwent significant enrichment of Ba and Sr through the fractionation of Mg-rich minerals within upper crust (3.1–4.4 kbar). Clinopyroxene, plagioclase and biotite in the Tiechang gabbro all contain lower Ba and Sr than those in the Xinsi diorite, suggesting that their parental melts were also initially low in Sr and Ba and experienced enrichment of these elements during magma evolution at middle crustal levels (5.7–6.3 kbar). The low Ba and Sr concentrations and Sr/Y ratios for parental melts of the Xinsi diorite and Tiechang gabbro suggest their derivation from the partial melting of mantle sources with input from slab melts at shallow depths without involvement of abundant garnet in petrogenesis. This study demonstrates the importance of fractional crystallization in the genesis of low Sr/Y high-Mg andesitic rocks and is conflict with past views that their geochemical features were related to the involvement of adakitic melts in their mantle sources. Therefore, this study presents an alternative model for the production of low Sr/Y and high Sr/Y high-Mg andesitic rocks, particularly in the Late Archean, which reflects the intense melting of subducted slab at different depths in the hotter mantle regime at that time.

Mineralogy of the HSE in the subcontinental lithospheric mantle —An interpretive review

The highly siderophile elements (HSE: Os, Ir, Ru, Rh, Pt, Pd, Re, Au) exist in solid solution in accessory base-metal sulfides (BMS) as well as nano-to-micron scale minerals in rocks of the subcontinental lithospheric mantle (SCLM). The latter include platinum-group minerals (PGM) and gold minerals, which may vary widely in morphology, composition and distribution. The PGM form isolated grains often associated with larger BMS hosted in residual olivine, located at interstices in between peridotite-forming minerals or more commonly in association with metasomatic minerals (pyroxenes, carbonates, phosphates) and silicate glasses in some peridotite xenoliths. The PGM found inside residual olivine are mainly Os-, Ir- and Ru-rich sulfides and alloys. In contrast, those associated with metasomatic minerals or silicate glasses of peridotite xenoliths consist of Pt, Pd, and Rh bonded with semimetals like As, Te, Bi, and Sn. Nanoscale observations on natural samples along with the results of recent experiments indicate that nucleation of PGM is mainly related with the uptake of HSE by nanoparticles, nanominerals or nanomelts at high temperature (> 900 °C) in both silicate and/or sulfide melts, regardless of the residual or metasomatic origin of their host minerals. A similar interpretation can be assumed for gold minerals. Our observations highlight that nanoscale processes play an important role on the ore-forming potential of primitive mantle-derived magmas parental to magmatic-hydrothermal deposits enriched in noble metals. The metal inventory in these magmas could be related with the physical incorporation of HSE-bearing nanoparticles or nanomelts during processes of partial melting of mantle peridotite and melt migration from the mantle to overlying continental crust.

Origin and tectonic implications of Late Jurassic high-Mg diorites along the Bangong-Nujiang suture zone, Tibet

ABSTRACT The Shiquanhe-Num Co ophiolitic mélange belt (SNOB) is one of two such belts along the Bangong-Nujiang suture zone (BNSZ) separating the Lhasa and Qiantang terranes of central Tibet. This study reports new geochronological, petrological and geochemical data for high-Mg dioritic dikes intruding the Shiquanhe ophiolitic peridotite. Based on LA-ICP-MS zircon U–Pb dating, dioritic dikes yield a Late Jurassic age of 162.8 ± 1.3 Ma. These are high-Mg diorites (53.0%–56.8% SiO2, 7.07%–8.82% MgO) with moderate TiO2 (0.95%–1.01%), high K2O+Na2O (6.02%–8.01%), and high contents of Cr (150–182 ppm), Ni (91–145 ppm) and Th (2.8–5.9 ppm). They are very similar to sanukites of the Setouchi volcanic rock belt (SW Japan). Shiquanhe diorites have high Sr/Y ratios (up to 41.3), distinct positive Pb anomalies, negative Nb anomalies and continental crust-like trace element patterns without negative Eu anomalies (average Eu/Eu* = 0.96). These geochemical characteristics indicate that Shiquanhe diorities were derived by partial melting of mantle peridotite as a result of interaction with hydrous melts of subducted sediments. Similar high-Mg magmas are common in the early evolution of a new subduction zone. Integrated with field observations and results from other studies of Late Jurassic high-Mg andesites and diorites along the SNOB, we argue that the Shiquanhe high-Mg diorites formed at an early stage of northward subduction of the Bangong-Nujiang Tethys ocean (BNO) beneath the Qiangtang terrane. Therefore, these results provide critical constraints on the Jurassic tectonic evolution of the Shiquanhe-Num Co ophiolitic mélange belt and are significant for understanding the evolution of the BNO.

Transport of coexisting Ni-Cu sulfide liquid and silicate melt in partially molten peridotite

Transport of coexisting sulfide and silicate melts in partially molten peridotite contributes to the redistribution of chalcophile elements within the upper mantle as well as the genesis of magmatic Ni-Cu sulfide deposits, but has not been investigated systematically. Using laboratory experiments, theoretical calculations, and X-ray synchrotron microtomography, this study documents the topology and considers controls on the extraction of two immiscible liquids during partial melting of mantle peridotite. Under hydrostatic conditions, the measured dihedral angle at silicate melt-mineral-mineral junctions is 13.7–21.3°. Silicate melt is distributed along grain edges forming incompletely interconnected melt channels that disconnected by some dead ends at melt fractions ∼7–9 vol%. Application of theoretically predicted permeability (k∼10−14–10−16 m2) permits estimation of the extraction velocity of silicate melt of 0.7-11.1 μm/day within a single interconnected melt channel. In the absence of silicate melt, isolated sulfide droplets (3.77 vol%) show a sulfide-olivine-olivine dihedral angle of 91.5–101.3°. However, in the presence of silicate melt, sulfide droplets (average size ∼2.53 ± 2.14 μm, 1σ) are partially surrounded by silicate melt and stranded in triple junctions or melt pockets due to the limitation of the smallest dimension (0.3 μm) of melt channels. Thus, the extraction of sulfide liquid is highly restricted by these dead ends and the smallest dimension of melt channels during porous flow of silicate melt. In contrast, during large-strain shear deformation (strain ∼1.6–2.5), initially stranded sulfide droplets were elongated and extracted with silicate melt into liquid-rich sheets with a length of several hundred microns, constantly oriented at 14.3 ± 4.5° to the shear plane and antithetic to the shear direction. The angle is lower than that (18–30°) of those sheets containing sulfide liquid only, indicating that silicate melt dominates liquid-rich sheets. Driven by stress, silicate melt-dominated liquid-rich sheets open the appropriately oriented grain boundaries between silicate minerals, thus providing an efficient pathway for the extraction of sulfide liquid during deformation. When such sheet-like channels remain open, sulfide droplets (> millimeter-scale) can be potentially mobile through high strain domains of the upper mantle, contributing to the addition of chalcophile elements and the fertilization of the lithospheric mantle.

Density of NaAlSi2O6 Melt at High Pressure and Temperature Measured by In-Situ X-ray Microtomography

In this study, the volumetric compression of jadeite (NaAlSi2O6) melt at high pressures was determined by three-dimensional volume imaging using the synchrotron-based X-ray microtomography technique in a rotation-anvil device. Combined with the sample mass, measured using a high-precision analytical balance prior to the high-pressure experiment, the density of jadeite melt was obtained at high pressures and high temperatures up to 4.8 GPa and 1955 K. The density data were fitted to a third-order Birch-Murnaghan equation of state, resulting in a best-fit isothermal bulk modulus K T 0 of 10.8 − 5.3 + 1.9 GPa and its pressure derivative K T 0 ′ of 3.4 − 0.4 + 6.6 . Comparison with data for silicate melts of various compositions from the literature shows that alkali-rich, polymerized melts are generally more compressible than alkali-poor, depolymerized ones. The high compressibility of jadeite melt at high pressures implies that polymerized sodium aluminosilicate melts, if generated by low-degree partial melting of mantle peridotite at ~250–400 km depth in the deep upper mantle, are likely denser than surrounding mantle materials, and thus gravitationally stable.

Circa 2.5 Ga granitoids in the eastern North China craton: Melting from ca. 2.7 Ga accretionary crust

Abstract The Neoarchean crust-mantle interaction and crustal evolution of the North China craton are controversial and are instructive of the processes of continental crust growth and cratonic evolution. We present here a systematic study of the petrology, geochemistry, and geochronology of Neoarchean granitoids from the eastern North China craton to elucidate their petrogenesis and tectonic setting. The rocks were collected from the Jielingkou, Anziling, and Qinhuangdao plutons, and an amphibole-monzoporphyry dike in the Qinhuangdao pluton. Samples from the Jielingkou pluton, consisting dominantly of monzodiorite and diorite with minor monzonite and granodiorite, contain 52.2–64.4 wt% SiO2, 2.46–4.52 wt% MgO (Mg# = 0.41–0.54), 3.76–5.77 wt% Na2O, and K2O/Na2O ratios of 0.29–0.71. The Anziling pluton samples, comprising syenite and monzonite, display slightly higher SiO2 (60.9–66.7 wt%) and K2O/Na2O ratios (0.70–1.11), but lower MgO (1.54–2.33 wt%) and Mg# (0.40–0.47) values, compared to the Jielingkou rocks. The Qinhuangdao pluton samples, consisting mainly of granite and minor syenite and granodiorite, with some diorite and monzoporphyry dikes, are characterized by the highest SiO2 values (75.7–76.9 wt%) and K2O/Na2O ratios (0.73–1.41) and lowest MgO content (0.14–0.32 wt%) among the studied samples. The amphibole-monzoporphyry dike has intermediate SiO2 (56.3 wt%), high MgO (3.79 wt%), Na2O (5.55 wt%), and Mg# (0.45), and low K2O/Na2O ratio (0.66). Zircon U-Pb laser-ablation–inductively coupled plasma–mass spectrometry dating showed that all plutons have a ca. 2.5 Ga crystallization age. Zircon crystals have mildly positive εHf(t) values (+0.24 to +5.45) and a depleted mantle model age (TDM1) of ca. 2.7 Ga. We interpret the granitoid rocks as sanukitoid-related, Closepet-type granites, potassium-rich adakites, and potassium-rich granitoid rocks that crystallized in the late Neoarchean (2.5 Ga) and were derived from partial melting of mantle peridotite that was metasomatized with the addition of slab melt, thickened alkali-rich juvenile lower crust and juvenile metamorphosed tonalitic rocks. Mantle plume activity ca. 2.7 Ga is thought to have been responsible for the early Neoarchean tectono-thermal event in the eastern North China craton. This activity resulted in a major crustal accretion period in the craton, with subordinate crustal reworking at its margins. A steep subduction regime between ca. 2.55 Ga and ca. 2.48 Ga led to the remelting of older crustal material, with subordinate crustal accretion by magma upwelling from a depleted mantle source resulting in late Neoarchean underplating. This crustal reworking and underplating resulted in the widespread ca. 2.5 Ga plutons in the eastern North China craton. Continental crust growth in the North China craton thus occurred in multiple stages, in response to mantle plume activity, as well as protracted subduction-related granitoid magmatism during the Neoarchean.

Late Cretaceous volcanic rocks in the Sangri area, southern Lhasa Terrane, Tibet: Evidence for oceanic ridge subduction

Late Cretaceous magmatism in the southern Lhasa subterrane, Tibet, provides critical constraints on the subduction processes of the Neo-Tethyan oceanic plate. Here, we provide data on the whole-rock geochemistry, zircon UPb ages, trace element contents, and Hf isotopes of early Late Cretaceous volcanic rocks from Sangri County to Sangye Temple (SS) along the southern Lhasa subterrane. The SS volcanic rocks include basalts, andesites, and dacites. SIMS and LA–ICP–MS zircon UPb data indicate that the SS dacites were erupted at ca. 95 Ma, coeval with the early Late Cretaceous “flare-up” event in the southern Lhasa subterrane. The SS volcanic rocks belong to the calc-alkaline to high-K calc-alkaline series and have the geochemical features of subduction-related volcanic rocks with negative Nb, Ta, and Ti anomalies. The basalts have similar rare earth element (REE) patterns to E-MORB and are characterized by high Zr abundances (65–190 ppm) and Zr/Y ratios (3.3–6.5). They were possibly derived by high-degree partial melting of mantle peridotite that had been metasomatized by subduction-related fluids with an input of asthenospheric components. Positive whole-rock εNd(t) (+2.9 to +3.2) values for the andesites, and their variable Mg# values (35–61) and MgO (2.29–7.32 wt%), Cr (12–232 ppm), and Ni (10–127 ppm) contents can be attributed to medium-degree partial melting of mantle peridotite followed by fractional crystallization of clinopyroxene and olivine. The calc-alkaline SS dacites are similar to adakites with high Sr (663–1188 ppm) and low heavy rare earth element (HREE) and Y (10.7–11.5 ppm) contents. These adakitic dacites have positive whole-rock εNd(t) (+2.9 to +3.4) and zircon εHf(t) (+8.4 to +14.9) values with relatively high values of Mg# (36–57) and high contents of compatible elements, indicating that they were derived from the partial melting of subducted oceanic slab, and with the ascending magma interacting with mantle wedge peridotite. Our new data indicate a distinct rock association of coeval asthenosphere-component-involved basalts and slab-derived adakitic dacites. Such an association, together with the coeval high-temperature charnockites and high-temperature granulite-facies metamorphism of the charnockitic country rocks in the southern Lhasa subterrane, indicates an anomalous input of materials and heat during the early Late Cretaceous “flare-up” event. Such an event can probably be attributed to the northwards subduction of a Neo-Tethyan oceanic ridge that allowed for contributions from upwelling asthenosphere that differed from the typical results of normal-angle subduction or low-angle/flat subduction and subsequent slab rollback.